Ionic Conductivity Studies on Proton Conducting Solid Biopolymer Electrolyte based on 2-Hydroxyethyl Cellulose (2HEC) Doped with Ammonium Chloride (NH4CL)

Abstract

Solution casting techniques have been used to create a solid biopolymer electrolyte (SBEs) based on 2-hydroxyethyl cellulose (2HEC) doped with varying amounts of ammonium chloride (NH₄Cl) to investigate the potential of NH₄Cl in enhancing the ionic conductivity of SBE. Electrical impedance spectroscopy (EIS) was used to measure the impedance of the electrolytes between 50 Hz and 1 MHz in frequency. At room temperature, ionic conductivity was at its highest for 16% weight percent of NH₄Cl which was 1.74 x 10^-3 Scm^-1. The temperature dependence data of 2HEC-NH₄Cl SBEs abides Arrhenius behaviour. Complex electrical modulus and complex permittivity were used to assess the dielectric data for the sample at various temperatures.