A Novel Poly (vinylidene) Fluoride/TiO2/Spent Bleaching Earth for Enhancing Hydrophilic Hollow Fibre Membrane
DOI:
https://doi.org/10.37934/cfdl.16.10.112125Keywords:
SBE, PVDF, hollow fiber membrane, hydrophilicAbstract
Nowadays, polymer as the raw material has been utilized in the development of Hollow Fibre (HF) membranes. PVDF is a commonly used for HF membrane material. However, it has hydrophobicity properties and lead membrane becomes low permeability and fouling. Therefore, to avoid these membranes problems, the incorporation of inorganic nanoparticles into PVDF membranes matrix is necessary to be applied for significantly improving PVDF membranes performance. This study investigates the characteristics and performance of PVDF-TiO2 HF membranes using spent bleaching earth (SBE) as a promising material from industrial waste as a renewable inorganic nanoparticle. This novel PVDF-TiO2-SBE HF membrane was fabricated using the subsequent steps: The preparation process incorporates SBE revival through solvent extraction and thermal treatment alongside the wet spinning technique for membrane fabrication. The Fourier transform infrared (FTIR) functional groups, scanning electron microscope (SEM) morphology, water contact angle and pure water flux performance were investigated to specifically understand the performance of this typical HF membranes. The IR results show that Si-O-Si groups were found in the membrane matrices due to the addition of SBE material. The addition of TiO2-SBE particles also indicate a sandwich (sponge-finger-like) morphological structure on the cross-sectional, a rough and porous surface structures. The hydrophilic properties of the HF membrane and pure water flux performance are determined by the composition of the TiO2-SBE mixture added as an additive material. The minimum contact angle found at 74.33°, while the water flux is 5.81 kg.m-2.h-1 on the identical HF membrane. Accordingly, this approach significantly enhances the properties of the pure PVDF HF membrane.
References
Elma, M., Y. Mawaddah, L. S. Wati, A. Sumardi, E. L. A. Rampun, and A. Rahma. "TEOS/TEVS membrane by dual acid-base catalyzed in seawater desalination with different temperature feeds." In AIP Conference Proceedings, vol. 2711, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0137740.
Pratiwi, Elsa Nadia, Muthia Elma, Mahmud Mahmud, Basir Basir, Mita Riani Rezki, Era Nandita Radiya Oktaviana, Siti Fatimah, Gesit Satriaji Saputro, Erdina Lulu Atika Rampun, and Aulia Rahma. "Novel carbon templated silica membrane prepared from Nypa fruticans leaf for seawater desalination." In AIP Conference Proceedings, vol. 2682, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0114125.
Elma, Muthia, Lilis Septyaningrum, Rahmawati Rahmawati, and Aulia Rahma. "Vacuum versus air calcination of modified TEOS-MTES based membrane for seawater desalination." In AIP Conference Proceedings, vol. 2711, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0137739.
Suhendra, Satria Anugerah, Muthia Elma, Isna Syauqiyah, Dwi Resa Lamandau, Siti Fatimah, and Aulia Rahma. "Energy from Salinity Gradient of Wetland Saline Water Using Reverse Electrodialysis Membrane." Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 101, no. 2 (2023): 46-59. https://doi.org/10.37934/arfmts.101.2.4659.
Mahmod, Safa Senan, Mohd Sobri Takriff, Maha Mohammad AL-Rajabi, Peer Mohamed Abdul, Ahmad Anas Nagoor Gunny, Hemavathi Silvamany, and Jamaliah Md Jahim. "Water reclamation from palm oil mill effluent (POME): Recent technologies, by-product recovery, and challenges." Journal of Water Process Engineering 52 (2023): 103488. https://doi.org/10.1016/j.jwpe.2023.103488.
Elma, Muthia, Muhammad Roil Bilad, Amalia Enggar Pratiwi, Aulia Rahma, Zaini Lambri Asyyaifi, Hairullah Hairullah, Isna Syauqiah, Yulian Firmana Arifin, and Riani Ayu Lestari. "Long-term performance and stability of interlayer-free mesoporous silica membranes for wetland saline water pervaporation." Polymers 14, no. 5 (2022): 895. https://doi.org/10.3390/polym14050895.
Muthia Elma, Amalia Enggar Pratiwi, Aulia Rahma, Erdina Lulu Atika Rampun, Mahmud Mahmud, Chairul Abdi, Raissa Rosadi, Dede Heri Yuli Yanto, and Muhammad Roil Bilad. "Combination of Coagulation, Adsorption, and Ultrafiltration Processes for Organic Matter Removal from Peat Water." Sustainability 14, no. 1 (2022): 370.
Muthia Elma, Mahmud Mahmud, Nurul Huda, Zaini L Assyaifi, Elsa Nadia Pratiwi, Mita Riani Rezki, Dewi Puspita Sari, Erdina Lulu Atika Rampun, and Aulia Rahma. "PVDF-TiO2 Hollow Fibre Membrane For Water Desalination." Jurnal Riset Teknologi Pencegahan Pencemaran Industri 12, no. 1 (2021): 1-6. https://doi.org/10.21771/jrtppi.2021.v12.no1.p1-6.
Mitsuru Higa, Yuriko Kakihana, Takehiro Sugimoto, and Kakuya Toyota. "Preparation of PVA-based hollow fiber ion-exchange membranes and their performance for Donnan dialysis." Membranes 9, no. 1 (2019): 4. https://doi.org/10.3390/membranes9010004.
Sari, Dewi Puspita, Muthia Elma, Mahmud Mahmud, Basir Basir, Mita Riani Rezki, Rahmawati Rahmawati, Lilis Septyaningrum, Gesit Satriaji Saputro, and Aulia Rahma. "Fabrication of organo-silica thin film for water desalination from dual silicate precursor (tetraethylorthosilicate & methyltriethoxysilane)." In AIP Conference Proceedings, vol. 2682, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0114126.
Ramezani, Rouzbeh, Luca Di Felice, and Fausto Gallucci. "A review on hollow fiber membrane contactors for carbon capture: Recent advances and future challenges." Processes 10, no. 10 (2022): 2103. https://doi.org/10.3390/pr10102103.
Maulida, Noor Aisya, Siti Humaeroh Fitriah, Aliah Aliah, Erdina Lulu Atika Rampun, and Muthia Elma. "Preparation and performance of interlayer-free organosilica membranes on zirconia support." In AIP Conference Proceedings, vol. 2667, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0112161.
Elma, Muthia, Erdina LA Rampun, Aulia Rahma, Zaini L. Assyaifi, Anna Sumardi, Aptar E. Lestari, Gesit S. Saputro, Muhammad Roil Bilad, and Adi Darmawan. "Carbon templated strategies of mesoporous silica applied for water desalination: A review." Journal of Water Process Engineering 38 (2020): 101520. https://doi.org/10.1016/j.jwpe.2020.101520.
Pradhana, E. A., M. Elma, M. H. D. Othman, N. Huda, M. D. Ul-Haq, Erdina LA Rampun, and A. Rahma. "The functionalization study of PVDF/TiO2 hollow fibre membranes under vacuum calcination exposure." In Journal of Physics: Conference Series, vol. 1912, no. 1, p. 012035. IOP Publishing, 2021.
M Elma, A Rahma, FR Mustalifah, A Rahman Wahid, DR Lamandau, S Fatimah, MS Huda, MA Alsiren, NKDA Saraswati, and PFA Simatupang, Nanofiltration Technology Applied for Peat and Wetland Saline Water, in Nanofiltration Membrane for Water Purification. 2023, Springer. p. 217-245. https://doi.org/10.1007/978-981-19-5315-6_12.
Elma, Muthia, Rhafiq Abdul Ghani, Aulia Rahma, Alya Dita Alyanti, and Novrian Dony. "Banana peels pectin templated silica ultrafiltration membrane in disk plate configuration applied for wetland water treatment." Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 100, no. 1 (2022): 77-88.
Nasrollahi, Nazanin, Leila Ghalamchi, Vahid Vatanpour, Alireza Khataee, and Maryam Yousefpoor. "Novel polymeric additives in the preparation and modification of polymeric membranes: A comprehensive review." Journal of Industrial and Engineering Chemistry 109 (2022): 100-124.https://doi.org/10.1016/j.jiec.2022.02.036.
Mohamed, Mohamed Azuwa, J. Jaafar, A. F. Ismail, M. H. D. Othman, and M. A. Rahman. "Fourier transform infrared (FTIR) spectroscopy." In Membrane characterization, pp. 3-29. elsevier, 2017. https://doi.org/10.1016/B978-0-444-63776-5.00001-2.
Ghani, R. A., M. Elma, R. A. Lestari, A. Alsiren, and A. Rahma. "Characterization of sprayable mulch film from yam nagara starch for agricultural application." In IOP Conference Series: Earth and Environmental Science, vol. 1184, no. 1, p. 012012. IOP Publishing, 2023.
Wei, Dongyang, Shouyong Zhou, Meisheng Li, Ailian Xue, Yan Zhang, Yijiang Zhao, Jing Zhong, and Dawei Yang. "PVDF/palygorskite composite ultrafiltration membranes: Effects of nano-clay particles on membrane structure and properties." Applied Clay Science 181 (2019): 105171. https://doi.org/10.1016/j.clay.2019.105171.
Wenten, I. G., K. Khoiruddin, A. K. Wardani, P. T. P. Aryanti, D. I. Astuti, and A. A. I. A. S. Komaladewi. "Preparation of antifouling polypropylene/ZnO composite hollow fiber membrane by dip-coating method for peat water treatment." Journal of Water Process Engineering 34 (2020): 101158.https://doi.org/10.1016/j.jwpe.2020.101158.
Rahma, Aulia, Muthia Elma, Muhammad Roil Bilad, Abdul Rahman Wahid, Muhammad Sirajul Huda, and Dwi Resa Lamandau. "Novel spent bleaching earth industrial waste as low-cost ceramic membranes material: elaboration and characterization." Materials Today: Proceedings 87 (2023): 136-140. https://doi.org/10.1016/j.matpr.2023.02.387.
Eliche-Quesada, D., and F. A. Corpas-Iglesias. "Utilisation of spent filtration earth or spent bleaching earth from the oil refinery industry in clay products." Ceramics International 40, no. 10 (2014): 16677-16687. https://doi.org/10.1016/j.ceramint.2014.08.030.
Muhamad, N. A. S., N. M. Mokhtar, W. J. Lau, A. F. Ismail, and R. Naim. "Fouling studies on hydrophobic PVDF-bentonite hollow fiber membrane during membrane distillation of palm oil mill effluent." Journal of Water Process Engineering 49 (2022): 102969. https://doi.org/10.1016/j.jwpe.2022.102969.
Kurada, Krishnasri V., Madhurima Dutta, Animesh Jana, and Sirshendu De. "Solubility parameter estimation and phase inversion modeling of bentonite‐doped polymeric membrane systems." Journal of Applied Polymer Science 137, no. 10 (2020): 48450. https://doi.org/10.1002/app.48450.
Paramitha, Tika, Johnner P. Sitompul, and Hyung Woo Lee. "The effect of organobentonites from spent bleaching earth (SBE) and commercial bentonite on nanocomposite properties." International Journal of Engineering & Technology 7, no. 4 (2018): 2000-2005. https://doi.org/10.14419/ijet.v7i4.15317.
Phey, Melissa Low Phey, Tuan Amran Tuan Abdullah, Arshad Ahmad, and Umi Fazara Md Ali. "Application of regenerated spent bleaching earth as an adsorbent for the carbon dioxide adsorption by gravimetric sorption system." In Journal of Physics: Conference Series, vol. 2259, no. 1, p. 012015. IOP Publishing, 2022.
Naser, Jamil, Onoriode P. Avbenake, Fadimatu N. Dabai, and Baba Y. Jibril. "Regeneration of spent bleaching earth and conversion of recovered oil to biodiesel." Waste Management 126 (2021): 258-265. https://doi.org/10.1016/j.wasman.2021.03.024.
Yulikasari, Andriyan, Ervin Nurhayati, Widya Utama, and Idaa Warmadewanthi. "Characterization of spent bleaching earth as an adsorbent material for dye removal." Journal of Ecological Engineering 23, no. 4 (2022). http://dx.doi.org/10.12911/22998993/146353.
Sumardi, Anna, Muthia Elma, Erdina Lulu Atika Rampun, Aptar Eka Lestari, Zaini Lambri Assyaifi, Adi Darmawan, Dede Heri Yuli Yanto, Isna Syauqiah, Yanti Mawaddah, and Linda Suci Wati. "Designing a mesoporous hybrid organo-silica thin film prepared from an organic catalyst." Membrane Technology 2021, no. 2 (2021): 5-8. https://doi.org/10.1016/S0958-2118(21)00029-X.
Li, Yanhong, Zhiwei Li, Yanjuan Li, Wenxue Guan, Yangyang Zheng, Xuemin Zhang, and Sanfan Wang. "Preparation and Electrochemical Characterization of Organic–Inorganic Hybrid Poly (Vinylidene Fluoride)-SiO2 Cation-Exchange Membranes by the Sol-Gel Method Using 3-Mercapto-Propyl-Triethoxyl-Silane." Materials 12, no. 19 (2019): 3265. https://doi.org/10.3390/ma12193265.
Kong, Fanrong, Wenying Zhou, Weiwei Peng, Chen Liang, Hongju Wu, Na Lin, Guangheng Wang, Dengfeng Liu, Aihong Feng, and Xiangrong Liu. "Interface modified Si@ SiO2/PVDF composite dielectrics with synchronously ameliorative dielectric and mechanical properties." Journal of Applied Polymer Science 140, no. 31 (2023): e54214. https://doi.org/10.1002/app.54214.
Pramono, Edi, Gadis Prihatin Wahyu Sejati, Sayekti Wahyuningsih, and Candra Purnawan. "Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration." Indonesian Journal of Chemistry 23, no. 2 (2023): 425-437. https://doi.org/10.22146/ijc.78979.
Muhfadzallah, Muhfadzallah, Umi Fathanah, Sri Aprilia, Syawaliah Muchtar, and Mukramah Yusuf. "Modifikasi membran polyvinylidene fluoride (PVDF) dengan penambahan polyvinyl pyrrolidone (PVP) dan kitosan dengan metode inversi fasa." Jurnal Litbang Industri 12, no. 2 (2022): 105-114. http://dx.doi.org/10.24960/jli.v12i2.7726.105-114.
Dzinun, Hazlini, Mohd Hafiz Dzarfan Othman, Ahmad F. Ismail, Mohd Hafiz Puteh, Mukhlis A. Rahman, Juhana Jaafar, Nadia Adrus, and Nur Awanis Hashim. "Antifouling behavior and separation performance of immobilized TiO2 in dual layer hollow fiber membranes." Polymer Engineering & Science 58, no. 9 (2018): 1636-1643. https://doi.org/10.1002/pen.24753.
Pratiwi, Amalia Enggar, Muthia Elma, Aulia Rahma, Erdina LA Rampun, and Gesit Satriaji Saputro. "Deconvolution of pectin carbonised template silica thin-film: synthesis and characterisation." Membrane Technology 2019, no. 9 (2019): 5-8. https://doi.org/10.1016/S0958-2118(19)30167-3.
Kamaludin, Roziana, Amir Syarifuddin Mohamad Puad, Mohd Hafiz Dzarfan Othman, Siti Hamimah Sheikh Abdul Kadir, and Zawati Harun. "Incorporation of N-doped TiO2 into dual layer hollow fiber (DLHF) membrane for visible light-driven photocatalytic removal of reactive black 5." Polymer Testing 78 (2019): 105939. https://doi.org/10.1016/j.polymertesting.2019.105939.
Qua, Marn Soon, Yan Zhao, Junyou Zhang, Sebastian Hernandez, Aung Thet Paing, Karikalan Mottaiyan, Jian Zuo, Adil Dhalla, Tai-Shung Chung, and Chakravarthy Gudipati. "Novel sandwich-structured hollow fiber membrane for high-efficiency membrane distillation and scale-up for pilot validation." Membranes 12, no. 4 (2022): 423. https://doi.org/10.3390/membranes12040423.
Febriyanti, Retno, Muthia Elma, Iryanti Fatyasari Nata, Ni Kadek Devi Ananda Saraswati, and Paskah Fransiska Afrida Simatupang. "Hydrogel Films Derived Water Hyacinth Stems And Banana Peels Pectin: Tensile Performance And Swelling Ability." Elkawnie: Journal of Islamic Science and Technology 9, no. 1 (2023): 81-98. http://dx.doi.org/10.22373/ekw.v9i1.16419.
Elma, Muthia, Ni Kadek Devi Ananda Saraswati, Paskah Fransiska Afrida Simatupang, Retno Febriyanti, Aulia Rahma, and Fitri Ria Mustalifah. "Hydrogel derived from water hyacinth and pectin from banana peel as a membrane layer." Materials Today: Proceedings 87 (2023): 13-17. https://doi.org/10.1016/j.matpr.2023.01.368.
Rahma, Aulia, Muthia Elma, Amalia E. Pratiwi, and Erdina LA Rampun. "Performance of interlayer-free pectin template silica membranes for brackish water desalination." Membrane Technology 2020, no. 6 (2020): 7-11. https://doi.org/10.1016/S0958-2118(20)30108-7.
Dzinun, Hazlini, Mohd Hafiz Dzarfan Othman, A. F. Ismail, Mohd Hafiz Puteh, Mukhlis A. Rahman, and Juhana Jaafar. "Morphological study of co-extruded dual-layer hollow fiber membranes incorporated with different TiO2 loadings." Journal of Membrane Science 479 (2015): 123-131. https://doi.org/10.1016/j.memsci.2014.12.052.
Rahma, Aulia, Muthia Elma, Erdina Lulu Atika Rampun, Amalia Enggar Pratiwi, Arief Rakhman, and Fitriani Fitriani. "Rapid thermal processing and long term stability of interlayer-free silica-P123 membranes for wetland saline water desalination." Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 71, no. 2 (2020): 1-9. https://doi.org/10.37934/arfmts.71.2.19.
Pramono, Edi, Rifki Alfiansyah, Muhamad Ahdiat, Deana Wahyuningrum, and Cynthia Linaya Radiman. "Hydrophilic poly (vinylidene fluoride)/bentonite hybrid membranes for microfiltration of dyes." Materials Research Express 6, no. 10 (2019): 105376. https://doi.org/10.1088/2053-1591/ab42e9.
Kusworo, Tutuk Djoko, Monica Yulfarida, Andri Cahyo Kumoro, and Dani Puji Utomo. "Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO2 membrane." Chinese Journal of Chemical Engineering 55 (2023): 123-136. https://doi.org/10.1016/j.cjche.2022.04.028.
Elma, Muthia, Eggy A. Pradana, Muhammad D. Ul-haq, Erdina LA Rampun, Aulia Rahma, Awali SK Harivram, Zaini L. Assyaifi, and Yayan Kamelia. "Hollow fiber membrane applied for Sasirangan wastewater desalination integrated with photocatalysis and pervaporation set-up." Materials Today: Proceedings 51 (2022): 1298-1302. https://doi.org/10.1007/s13726-019-00700-y.
Lestari, Riani Ayu, Muthia Elma, Aulia Rahma, Dewi Suparsih, Syarifah Anadhliyah, Norlian Ledyana Sari, Dhimas Ari Pratomo et al. "Organo silica membranes for wetland saline water desalination: effect of membranes calcination temperatures." In E3S Web of Conferences, vol. 148, p. 07006. EDP Sciences, 2020. https://doi.org/10.1051/e3sconf/202014807006.
Kamaludin, Roziana, Lubna Abdul Majid, Mohd Hafiz Dzarfan Othman, Sumarni Mansur, Siti Hamimah Sheikh Abdul Kadir, Keng Yinn Wong, Watsa Khongnakorn, and Mohd Hafiz Puteh. "Polyvinylidene Difluoride (PVDF) hollow fiber membrane incorporated with antibacterial and anti-fouling by Zinc Oxide for water and wastewater treatment." Membranes 12, no. 2 (2022): 110. https://doi.org/10.3390/membranes12020110.
Pramono, Edi, Gadis Prihatin Wahyu Sejati, Sayekti Wahyuningsih, and Candra Purnawan. "Polyvinylidene Fluoride (PVDF)/Modified Clay Hybrid Membrane for Humic Acid and Methylene Blue Filtration." Indonesian Journal of Chemistry 23, no. 2 (2023): 425-437.
Li, Hongbin, Mengjie Fan, Linmao Li, Sisi Ma, Wenying Shi, and Jie Liu. "Enhanced water permeability of hollow fiber composite reverse osmosis membrane using porous α-cellulose/polysulfone hollow fiber membrane as the substrate." Textile Research Journal 93, no. 19-20 (2023): 4433-4450. https://doi.org/10.1177/00405175231176860.
Parvizian, Fahime, Fatemeh Ansari, and Samaneh Bandehali. "Oleic acid-functionalized TiO2 nanoparticles for fabrication of PES-based nanofiltration membranes." Chemical Engineering Research and Design 156 (2020): 433-441. https://doi.org/10.1016/j.cherd.2020.02.019.
Elma, M., D. R. Mujiyanti, N. M. Ismail, M. R. Bilad, A. Rahma, S. K. Rahman, A. Rakhman, and E. L. A. Rampun. "Development of hybrid and templated silicaâ p123 membranes for brackish water desalination." Polymers 12, no. 11 (2020): 1-13. https://doi.org/10.3390/polym12112644.
Elma, Muthia, Aulia Rahma, Amalia E. Pratiwi, and Erdina LA Rampun. "Coagulation as pretreatment for membrane‐based wetland saline water desalination." Asia‐Pacific Journal of Chemical Engineering 15, no. 4 (2020): e2461. https://doi.org/10.1002/apj.2461.
Elma, M., Y. Mawaddah, L. S. Wati, A. Sumardi, E. L. A. Rampun, and A. Rahma. "TEOS/TEVS membrane by dual acid-base catalyzed in seawater desalination with different temperature feeds." In AIP Conference Proceedings, vol. 2711, no. 1. AIP Publishing, 2023. https://doi.org/10.1063/5.0137740.
Muhamad, N. A. S., N. M. Mokhtar, W. J. Lau, A. F. Ismail, and R. Naim. "Fouling studies on hydrophobic PVDF-bentonite hollow fiber membrane during membrane distillation of palm oil mill effluent." Journal of Water Process Engineering 49 (2022): 102969.
Yi, C. Wan, N. Hwee Xin, and N. M. Mokhtar. "Development of Bench-Scale Direct Contact Membrane Distillation System for Treatment of Palm Oil Mill Effluent." Journal of Applied Membrane Science & Technology 27, no. 2 (2023): 103-113. https://doi.org/10.11113/amst.v27n2.271.
